02 : Research

Lunar pyroclastic glass beads preserve a record of physical and chemical conditions within volcanic gas clouds inthe form of nanoscale minerals vapour-deposited onto their surfaces. However, the scale of these mineral deposits - less than 100 nm - has presented challenges for detailed analysis. Using SEM, TEM, APT, and NanoSIMS, we analysed pristine black glass beads from Apollo drive tube 74001 and found a sequence of sulfide depositionthat directly evidences lunar gas cloud evolution. The deposits are predominantly micromound structures ofnanopolycrystalline sphalerite ((Zn,Fe)S), with iron enrichment at the bead-micromound interface. Thermo-chemical modelling indicates that hydrogen and sulfur were major elements within the volcanic plume and tiesthe iron gradient to decreasing gas pressure during deposition. This pressure drop may also be consistent withour observed trend of potential δ34 S depletion. Finally, Apollo 17 74220 orange beads, deposited higher in the Shorty Crater sequence, appear to lack abundant ZnS nanocrystals (Liu and Ma, 2024a), suggesting a change invapour deposition between orange- and black-glass bead deposition. Together, our results suggest a change ineruption style over the course of a pyroclastic volcanic eruption in the Taurus-Littrow Valley.

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High ³He/⁴He ratios in Ocean Island Basalts (OIBs) are viewed as evidence for sampling of an undegassed primitive mantle source by mantle plumes. However, this does not explain why helium concentrations and the elemental ratios He/Ar and He/Ne in OIBs are an order of magnitude lower than in Mid-Ocean Ridge Basalts (MORBs). This discrepancy, often referred to as the 'Helium Paradox', challenges our understanding of mantle degassing processes. Various studies invoke disequilibrium degassing as the solution to this problem [Gonnermann and Mukhopadhyay (2007), Weston (2015)]. However, there is significant disagreement between current models.

In response to these unresolved questions, we are developing a new model that more accurately reflects the behavior of gas bubbles during the degassing of noble gases. We employ a lattice Boltzmann method for free surface flows, based on the approach of Körner et al. (2005). This method is particularly suited for our purposes as it can simulate the solubility-pressure relationships of CO₂ and noble gases, account for hydrodynamic interactions between bubbles, and, importantly, model the nucleation of new bubbles driven by volatile supersaturation.

Such nucleation events are critical during the ascent of magma, as they can counteract kinetic fractionation by reducing the diffusional length scale. To the best of our knowledge, ours is the first degassing model to incorporate the nucleation of new bubbles with realistic physics, Through this work, we aim to offer a more comprehensive framework for interpreting noble gas signatures in MORBs and OIBs, thereby addressing a key aspect of the Helium Paradox.